I'm Helen from Shopify Support. Great question!
To remove a store from single sign on (SSO), you need to create a staff account with the email address and password that you would like to use, and then transfer ownership of the store over to that account. This will set the new account as the Account Owner, and thus remove it from your SSO.
The steps to transfer account ownership are found in our Help Doc here.
All the best,
Helen | Social Care @ Shopify
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