No, you cannot activate your Payoneer account on Shopify without approval. In order to use Payoneer as a payment method on Shopify, you need to first apply for Payoneer and get approved. Once approved, you can connect your Payoneer account to your Shopify store and start accepting payments.
It is important to note that Shopify has its own payment gateway, called Shopify Payments, which is available in many countries. If you are unable to use Payoneer, you can consider using Shopify Payments or other third-party payment gateways supported by Shopify.
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