The only “solution” I have found for a customer that belatedly provides their tax exempt certificate for a fulfilled order is to 1) flag the account as tax exempt 2) pretend the order is an RMA and go through the entire “Return” process 3) add the products back into the same order and they should come in w/o the sales tax being added. Ridiculous, I know, but that is the only workaround I’ve found.
All software has quirks, but this one seems a little silly, along with the coupon/discount refund issue. The only way I’ve seen the sales tax is reduced, after an order is placed, is if one of the products is removed using the Edit function. This must be done before an order is fulfilled and archived.